Search results for "fluctuation [geometry]"

showing 5 items of 15 documents

Brownian dynamics simulation of grafted polymer brushes

1995

We present results of computer simulations by the method of Brownian dynamics of polymeric brushes attached to impenetrable planes. For testing both model and method we have used one polymer brush attached to a repulsive plane and compare some results with Monte Carlo results of Lai and Binder on the bond fluctuation model. We have also studied two polymeric brushes attached to two parallel planes at different distances between planes, and investigate the interplay between the interpenetration of the brushes and the configurational properties of the grafted chains.

chemistry.chemical_classificationQuantitative Biology::BiomoleculesPolymers and PlasticsChemistryPlane (geometry)Organic ChemistryMonte Carlo methodPolymerCondensed Matter PhysicsPolymer brushdigestive systemCondensed Matter::Soft Condensed MatterInorganic ChemistryComputer Science::GraphicsIntermolecular interactionChemical physicsMaterials ChemistryBrownian dynamicsStatistical physicsStructure factorBond fluctuation modelMacromolecular Theory and Simulations
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Comb-Branched Polymers:  Monte Carlo Simulation and Scaling

1996

The Monte Carlo simulation technique (the bond fluctuation model) has been used for the study of the equilibrium conformations of comb-branched polymers consisting of a long flexible main chain and side chains grafted at a regular separation onto the main chain. The solvent has been supposed to be good (athermal) for the main and side chains. The global conformation and the gyration radius of the polymer, as well as the local conformational structure of the comb, have been analyzed as functions of the length of the side chains and spacers. The effect of induced rigidity of the comb due to the interaction between side chains has been observed. We have found the results of the simulation to b…

chemistry.chemical_classificationQuantitative Biology::BiomoleculesPolymers and PlasticsOrganic ChemistryMonte Carlo methodPhysics::OpticsPolymerGyrationCondensed Matter::Soft Condensed MatterInorganic ChemistryRigidity (electromagnetism)chemistryChemical physicsMaterials ChemistrySide chainRadius of gyrationStatistical physicsScalingBond fluctuation modelMacromolecules
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Entropy theory and glass transition: A test by Monte Carlo simulation

1997

This article reviews the results of a test of the Gibbs-DiMarzio theory by Monte Carlo Simulation. The simulation employed the bond-fluctuation model on a simple cubic lattice. This model incorporates two kinds of interactions: the excluded volume interaction among all monomers of the melt and an internal energy of the chains, which favors large bonds and makes the chains stiffen with decreasing temperature. The stiffening of the chains leads to an increase of their volume requirements, which competes with the packing constraints at low temperatures. This competition strongly slows down the structural relaxation of the melt and induces the glassy behavior. The model therefore takes into acc…

chemistry.chemical_classificationQuantitative Biology::Biomoleculesbond-fluctuation modelMaterials scienceInternal energyMonte Carlo methodGibbs-DiMarzio theoryGeneral EngineeringThermodynamicsSimple cubic latticePolymerArticleStiffeningCondensed Matter::Soft Condensed Matterentropy measurementchemistryExcluded volumeAdam-Gibbs theoryEntropy (information theory)chemical potentialglass transitionStatistical physicsdiffusion coefficientGlass transitionMonte Carlo simulation
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Quantum fluctuations and correlations in equilibrium and nonequilibrium thermodynamics

2014

heat capacitythermodynamicquantum fluctuationgaussian approximationopen systemsfluctuation theorementanglementnon-Markovianityentropy productionquantum correlationSettore FIS/03 - Fisica Della Materia
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Unraveling the nature of universal dynamics in O(N) theories

2020

Many-body quantum systems far from equilibrium can exhibit universal scaling dynamics which defy standard classification schemes. Here, we disentangle the dominant excitations in the universal dynamics of highly occupied N-component scalar systems using unequal-time correlators. While previous equal-time studies have conjectured the infrared properties to be universal for all N, we clearly identify for the first time two fundamentally different phenomena relevant at different N. We find all N >= 3 to be indeed dominated by the same Lorentzian "large-N" peak, whereas N = 1 is characterized instead by a non-Lorentzian peak with different properties, and for N = 2, we see a mixture of two cont…

phase space methodsquasiparticlescollective excitationsnonequilibrium systemsbose gasesfluctuation theoremsscaling laws of complex systems
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